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One expensive item that can easily be made yourself, and at a huge fraction of the store bought cost, is laundry detergent. You can make both liquid and powdered versions, but I currently enjoy the powdered version as it is a less involved process to make it and it also packs up nicely for storage. You can store it in a small tupperware or jar. I naturally like to keep mine in an old container that most people would've tossed in the recycling bin after using its contents.
So, here is my recipe for laundry detergent:
Use a grater to grate 1 cup of a biodegradable, vegetable based (castille) bar soap (I like Dr. Bronner's or Mrs. Meyers).
Mix 1 cup grated soap with
1/2 cup washing soda
1/2 cup borax
Use 1 tbsp for light loads; 2 tbsp for heavy loads
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